The ammonia evolved from the treatment of $0.30 \, g$ of an organic compound for the estimation of nitrogen was passed in $100 \, mL$ of $0.1 \, M$ sulphuric acid. The excess of acid required $20 \, mL$ of $0.5 \, M$ sodium hydroxide solution for complete neutralization. The organic compound is:

$A$ $2.0 \, g$ sample containing $MnO_2$ is treated with $HCl$ liberating $Cl_2$. The $Cl_2$ gas is passed into a solution of $KI$ and $60.0 \, mL$ of $0.1 \, M \, Na_2S_2O_3$ is required to titrate the liberated iodine. The percentage of $MnO_2$ in the sample is $.....$ (Nearest integer).
[Atomic masses (in $u$): $Mn = 55, Cl = 35.5, O = 16, I = 127, Na = 23, K = 39, S = 32$]

Given below are two statements: One is labelled as Assertion $A$ and the other is labelled as Reason $R$.
Assertion $A$: Permanganate titrations are not performed in the presence of hydrochloric acid.
Reason $R$: Chlorine is formed as a consequence of the oxidation of hydrochloric acid.
In the light of the above statements,choose the correct answer from the options given below.

The primary standard solution for the estimation of $Na_2S_2O_3$ is:

Why is it necessary to wash the precipitate before measuring it quantitatively?

When potassium permanganate is titrated against ferrous ammonium sulphate,the equivalent weight of potassium permanganate is