The $E^{\Theta} (M^{2+} / M)$ value for copper is positive $(+0.34 \ V)$. What is the possible reason for this? (Hint: consider its high $\Delta_{a} H^{\Theta}$ and low $\Delta_{hyd} H^{\Theta}$)

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) The $E^{\Theta} (M^{2+} / M)$ value of a metal depends on the energy changes involved in the following steps:
$1.$ Sublimation: The energy required for converting one mole of an atom from the solid state to the gaseous state.
$M_{(s)} \longrightarrow M_{(g)}$ $\Delta_{a} H^{\Theta}$ (Atomization energy)
$2.$ Ionization: The energy required to remove electrons from one mole of atoms in the gaseous state.
$M_{(g)} \longrightarrow M^{2+}_{(g)} + 2e^-$ $\Delta_{i} H^{\Theta}$ (Ionization energy)
$3.$ Hydration: The energy released when one mole of ions are hydrated.
$M^{2+}_{(g)} + aq \longrightarrow M^{2+}_{(aq)}$ $\Delta_{hyd} H^{\Theta}$ (Hydration energy)
The net energy change is the sum of these energies. Copper has a very high enthalpy of atomization $(\Delta_{a} H^{\Theta})$ and a relatively low enthalpy of hydration $(\Delta_{hyd} H^{\Theta})$. The sum of these energy terms is positive,which makes the overall $E^{\Theta} (M^{2+} / M)$ value for copper positive.

Explore More

Similar Questions

The element with which of the following outer electron configuration may exhibit the largest number of oxidation states in its compounds?

Compare the stability of the $+2$ oxidation state for the elements of the first transition series.

Assertion: Transition metals and their complexes show catalytic activity.
Reason: The activation energy of a reaction is lowered by the catalyst.

Which element among the following is ferromagnetic?

Which of the following elements does not exhibit variable valency?

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo