The $pH$ of blood does not appreciably change by a small addition of acid or a base because blood

The $pH$ of an aqueous solution containing $1 \ M$ benzoic acid $(pK_{a}=4.20)$ and $1 \ M$ sodium benzoate is $4.5$. The volume of benzoic acid solution in $300 \ mL$ of this buffer solution is . . . . . . $mL$.

$A$ student needs to prepare a buffer solution of propanoic acid and its sodium salt with $pH$ $4$. The ratio of $\frac{[CH_{3}CH_{2}COO^{-}]}{[CH_{3}CH_{2}COOH]}$ required to make the buffer is .....
Given: $K_{a}(CH_{3}CH_{2}COOH) = 1.3 \times 10^{-5}$

Calculate the $pH$ of a buffer solution containing $0.027 \ M$ weak acid and $0.054 \ M$ of its salt with a strong base,if the $pK_{a}$ is $4.2$.

$50 \, mL$ of $2 \, N$ acetic acid mixed with $10 \, mL$ of $1 \, N$ sodium acetate solution will have an approximate $pH$ of $(K_a = 10^{-5})$

The $pH$ of a solution containing $0.1 \ N$ $NH_4OH$ and $0.1 \ N$ $NH_4Cl$ is $9.25$. What is the $pK_b$ for $NH_4OH$?