Standard molar enthalpy of formation of $CO_2$ is equal to

Consider the following reactions:
$(i)$ $H_{(aq)}^{+} + OH^{-}_{(aq)} \longrightarrow H_2O_{(l)}$,$\Delta H = -X_1 \ kJ \ mol^{-1}$
$(ii)$ $H_{2_{(g)}} + \frac{1}{2} O_{2_{(g)}} \longrightarrow H_2O_{(l)}$,$\Delta H = -X_2 \ kJ \ mol^{-1}$
$(iii)$ $CO_{2_{(g)}} + H_{2_{(g)}} \longrightarrow CO_{(g)} + H_2O_{(l)}$,$\Delta H = -X_3 \ kJ \ mol^{-1}$
$(iv)$ $C_2H_{2_{(g)}} + \frac{5}{2} O_{2_{(g)}} \longrightarrow 2CO_{2_{(g)}} + H_2O_{(l)}$,$\Delta H = -X_4 \ kJ \ mol^{-1}$
Enthalpy of formation of $H_2O_{(l)}$ is

Hess's law is applicable for the determination of heat of

The heat of atomization of methane and ethane are $360 \ kJ/mol$ and $620 \ kJ/mol,$ respectively. The longest wavelength of light capable of breaking the $C-C$ bond is (Avogadro number $= 6.02 \times 10^{23},$ $h = 6.62 \times 10^{-34} \ J \cdot s$)

For which one of the following equations is $\Delta H_{react}^o$ equal to $\Delta H_f^o$ for the product?

Calculate the heat of formation of $Ca(OH)_{2(s)}$ at $1.8\,^{\circ}C$ from the following data:
$CaO_{(s)} + H_2O_{(l)} \to Ca(OH)_{2(s)}$; $\Delta H_{1.8\,^{\circ}C} = -15.26\,K\,cal$
$H_{2(g)} + \frac{1}{2}O_{2(g)} \to H_2O_{(l)}$; $\Delta H_{1.8\,^{\circ}C} = -68.37\,K\,cal$
$Ca_{(s)} + \frac{1}{2}O_{2(g)} \to CaO_{(s)}$; $\Delta H_{1.8\,^{\circ}C} = -151.80\,K\,cal$