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(D) The first compound is $2$-chlorobutan$-1$-ol $(CH_2(OH)-CHCl-CH_2-CH_3)$.The second compound is $3$-chlorobutan$-1$-ol $(CH_2(OH)-CH_2-CHCl-CH_3)$

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Structural isomers

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(D) The first compound is $2$-chlorobutan$-1$-ol $(CH_2(OH)-CHCl-CH_2-CH_3)$.The second compound is $3$-chlorobutan$-1$-ol $(CH_2(OH)-CH_2-CHCl-CH_3)$.Both compounds have the same molecular formula $(C_4H_9ClO)$ but differ in the position of the chlorine atom on the carbon chain.Therefore,they are positional isomers,which is a type of structural isomerism.

Identify the relationship between the given pair of compounds:

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