Redox reactions play a pivotal role in chemistry and biology. The values of standard redox potential $(E^{\circ})$ of two half-cell reactions decide which way the reaction is expected to proceed. $A$ simple example is a Daniel cell in which zinc goes into solution and copper gets deposited. Given below are a set of half-cell reactions (acidic medium) along with their $E^{\circ}$ ($V$ with respect to normal hydrogen electrode) values.
$I_2 + 2e^{-} \rightarrow 2I^{-} \quad E^{\circ} = 0.54 \ V$
$Cl_2 + 2e^{-} \rightarrow 2Cl^{-} \quad E^{\circ} = 1.36 \ V$
$Mn^{3+} + e^{-} \rightarrow Mn^{2+} \quad E^{\circ} = 1.50 \ V$
$Fe^{3+} + e^{-} \rightarrow Fe^{2+} \quad E^{\circ} = 0.77 \ V$
$O_2 + 4H^{+} + 4e^{-} \rightarrow 2H_2O \quad E^{\circ} = 1.23 \ V$
$1.$ Among the following,identify the correct statement.
$(A)$ Chloride ion is oxidized by $O_2$
$(B)$ $Fe^{2+}$ is oxidized by iodine
$(C)$ Iodide ion is oxidized by chlorine
$(D)$ $Mn^{2+}$ is oxidized by chlorine
$2.$ While $Fe^{3+}$ is stable,$Mn^{3+}$ is not stable in acid solution because
$(A)$ $O_2$ oxidizes $Mn^{2+}$ to $Mn^{3+}$
$(B)$ $O_2$ oxidizes both $Mn^{2+}$ and $Fe^{2+}$ to $Fe^{3+}$
$(C)$ $Fe^{3+}$ oxidizes $H_2O$ to $O_2$
$(D)$ $Mn^{3+}$ oxidizes $H_2O$ to $O_2$
$3.$ Sodium fusion extract,obtained from aniline,on treatment with iron$(II)$ sulphate and $H_2SO_4$ in presence of air gives a Prussian blue precipitate. The blue color is due to the formation of
$(A)$ $Fe_4[Fe(CN)_6]_3$
$(B)$ $Fe_3[Fe(CN)_6]_2$
$(C)$ $Fe_4[Fe(CN)_6]_2$
$(D)$ $Fe_3[Fe(CN)_6]_3$
Give the answer for questions $1, 2$ and $3.$

  • A
    $C, D, A$
  • B
    $B, D, B$
  • C
    $A, D, D$
  • D
    $C, B, C$

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The molar conductance of $NaCl$,$HCl$,and $CH_{3}COONa$ at infinite dilution are $126.45$,$426.16$,and $91.0 \ S \ cm^{2} \ mol^{-1}$ respectively. The molar conductance of $CH_{3}COOH$ at infinite dilution is. Choose the right option for your answer. (In $S \ cm^{2} \ mol^{-1}$)

For the reaction $4B_{(s)} + 3O_{2(g)} \rightarrow 2B_2O_{3(g)}$,the standard cell potential is $E^o_{cell} = 1.433 \ V$. Calculate the molar entropy $(S_m^o)$ of oxygen gas in $J/K \ mol$.
Given:
$(\Delta_fH^o)_{B_2O_3(g)} = -840 \ kJ/mol$
$(S_m^o)_{B_2O_3(g)} = 280 \ J/K \ mol$
$(S_m^o)_{B(s)} = 10 \ J/K \ mol$
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The process of rusting of iron occurs as follows:
$Fe \rightarrow Fe^{2+} + 2e^{-}, E^{o} = 0.44 \ V$
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Then for this reaction,$\Delta G^{o} = .... \ kJ/mol$

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Impure copper containing $Fe$,$Au$,and $Ag$ as impurities is electrolytically refined. $A$ current of $140 \ A$ for $482.5 \ s$ decreased the mass of the anode by $22.26 \ g$ and increased the mass of the cathode by $22.011 \ g$. The percentage of iron in the impure copper is (Given molar mass $Fe = 55.5 \ g \ mol^{-1}$,molar mass $Cu = 63.54 \ g \ mol^{-1}$)

Given below are two statements:
Statement $I$: For $KI$,molar conductivity increases steeply with dilution.
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