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Which of the following reactions results in the formation of a pair of diastereomers?

The end product $(C)$ of the following reaction is:

Arrange benzene,$n-$hexane and ethyne in decreasing order of acidic behaviour. Also give reason for this behaviour.

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Petroleum refining is:

The hydrocarbon $(X)$ with molar mass $80 \ g \ mol^{-1}$ and $90 \%$ carbon has $............$ degree of unsaturation.

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