Out of the following two coordination entitie | vedclass

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(A) coordination entity is chiral if it lacks a plane of symmetry and a center of inversion.$(a)$ The $cis-[CrCl_{2}(ox)_{2}]^{3-}$ isomer lacks both

Vedclass · Accepted Answer

$(a)$ $cis-[CrCl_{2}(ox)_{2}]^{3-}$

Vedclass · Answer

(A) coordination entity is chiral if it lacks a plane of symmetry and a center of inversion.$(a)$ The $cis-[CrCl_{2}(ox)_{2}]^{3-}$ isomer lacks both a plane of symmetry and a center of inversion,making it chiral (optically active).$(b)$ The $trans-[CrCl_{2}(ox)_{2}]^{3-}$ isomer possesses a plane of symmetry (and a center of inversion),making it achiral (optically inactive).Therefore,the $cis$ isomer is the chiral one.

Complex Ion	Label
$[Mn(CN)_6]^{3-}$	$A$
$[Fe(CN)_6]^{3-}$	$B$
$[CoF_6]^{3-}$	$C$
$[Co(C_2O_4)_3]^{3-}$	$D$

Out of the following two coordination entities,which is chiral (optically active)?
$(a)$ $cis-[CrCl_{2}(ox)_{2}]^{3-}$
$(b)$ $trans-[CrCl_{2}(ox)_{2}]^{3-}$

Similar Questions

Observe the following complex ions:
Complex Ion Label
$[Mn(CN)_6]^{3-}$ $A$
$[Fe(CN)_6]^{3-}$ $B$
$[CoF_6]^{3-}$ $C$
$[Co(C_2O_4)_3]^{3-}$ $D$

Identify the option in which the unpaired electrons in the complex ions are in correct increasing order.

Which of the following are diamagnetic?
$I. K_4[Fe(CN)_6]$
$II. K_3[Cr(CN)_6]$
$III. K_3[Co(CN)_6]$
$IV. K_2[Ni(CN)_4]$
Select the correct answer using the codes given below:

The two complexes given below are $............$.

In which of the following pairs do both the complexes show optical isomerism?

$Cis-trans$ isomerism is exhibited by

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Out of the following two coordination entities,which is chiral (optically active)?$(a)$ $cis-[CrCl_{2}(ox)_{2}]^{3-}$$(b)$ $trans-[CrCl_{2}(ox)_{2}]^{3-}$