One mole of $H_2O$ and one mole of $CO$ are taken in a $10 \ L$ vessel and heated to $725 \ K$. At equilibrium,$40 \%$ of water (by mass) reacts with $CO$ according to the equation:
$H_2O_{(g)} + CO_{(g)} \longleftrightarrow H_{2(g)} + CO_{2(g)}$
Calculate the equilibrium constant $(K_c)$ for the reaction.

  • A
    $0.44$
  • B
    $0.55$
  • C
    $0.66$
  • D
    $0.88$

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At $783 \, K$ in the reaction,$H_{2(g)} + I_{2(g)} \rightleftharpoons 2 HI_{(g)}$,the molar concentrations $(mol \, L^{-1})$ of $H_2, I_2$ and $HI$ at some instant of time are $0.1, 0.2$ and $0.4$,respectively. If the equilibrium constant is $46$ at the same temperature,then as the reaction proceeds:

$1 \ mol$ $N_2$ and $3 \ mol$ $H_2$ are taken in a $4 \ L$ closed vessel at a constant temperature. The reaction is $N_{2(g)} + 3H_{2(g)} \rightleftharpoons 2NH_{3(g)}$. If $0.25\%$ of $N_2$ is converted into ammonia,calculate $K_c$ for this reaction and the $K_c'$ for the reaction $\frac{1}{2}N_{2(g)} + \frac{3}{2}H_{2(g)} \rightleftharpoons NH_{3(g)}$.

The value of $K_{c} = 4.24$ at $800 \, K$ for the reaction,
$CO_{(g)} + H_{2}O_{(g)} \rightleftharpoons CO_{2(g)} + H_{2(g)}$
Calculate equilibrium concentrations of $CO_{2}$,$H_{2}$,$CO$ and $H_{2}O$ at $800 \, K$,if only $CO$ and $H_{2}O$ are present initially at concentrations of $0.10 \, M$ each.

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Ethyl acetate is formed by the reaction between ethanol and acetic acid and the equilibrium is represented as:
$CH_3COOH_{(l)} + C_2H_5OH_{(l)} \longleftrightarrow CH_3COOC_2H_{5(l)} + H_2O_{(l)}$
$(i)$ Write the concentration ratio (reaction quotient),$Q_c$,for this reaction (note: water is not in excess and is not a solvent in this reaction).
$(ii)$ At $293 \ K$,if one starts with $1.00 \ mol$ of acetic acid and $0.18 \ mol$ of ethanol,there is $0.171 \ mol$ of ethyl acetate in the final equilibrium mixture. Calculate the equilibrium constant.
$(iii)$ Starting with $0.5 \ mol$ of ethanol and $1.0 \ mol$ of acetic acid and maintaining it at $293 \ K$,$0.214 \ mol$ of ethyl acetate is found after sometime. Has equilibrium been reached?

In a $0.25 \ L$ tube,$4 \ mol$ of $NO$ undergoes dissociation. If the degree of dissociation is $10\%$,then the value of $K_c$ for the reaction $2NO \rightleftharpoons N_2 + O_2$ will be:

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