Of the following $0.10 \ m$ aqueous solutions,which one will exhibit the largest freezing point depression?

Considering acetic acid dissociates in water,its dissociation constant is $6.25 \times 10^{-5}$. If $5 \ mL$ of acetic acid is dissolved in $1 \ L$ water,the solution will freeze at $-x \times 10^{-2} \ {}^{\circ}C$,provided pure water freezes at $0 \ {}^{\circ}C$.
$x = . . . . . . . . .$ (Nearest integer)
Given: $(K_{f})_{\text{water}} = 1.86 \ K \ kg \ mol^{-1}$.
Density of acetic acid is $1.2 \ g \ mL^{-1}$.
Molar mass of water $= 18 \ g \ mol^{-1}$.
Molar mass of acetic acid $= 60 \ g \ mol^{-1}$.
Density of water $= 1 \ g \ cm^{-3}$.
Acetic acid dissociates as:
$CH_3COOH \rightleftharpoons CH_3COO^{-} + H^{+}$

$MX_{2}$ dissociates into $M^{2+}$ and $X^{-}$ ions in an aqueous solution,with a degree of dissociation $(\alpha)$ of $0.5$. The ratio of the observed depression of freezing point of the aqueous solution to the value of the depression of freezing point in the absence of ionic dissociation is

For a dilute aqueous solution of glucose,the van't Hoff factor $(i)$ is:

The elevation in boiling point of a solution of $13.44 \ g$ of $CuCl_2$ in $1 \ kg$ of water using the following information will be (Molecular weight of $CuCl_2 = 134.4 \ g \ mol^{-1}$ and $K_b = 0.52 \ K \ kg \ mol^{-1}$)

Which of the following equimolar aqueous solutions has the highest freezing point?