Nickel combines with a uninegative monodentate ligand $(X^{-})$ to form a paramagnetic complex $[NiX_4]^{2-}$. The hybridisation involved and the number of unpaired electrons present in the complex are respectively:

  • A
    $sp^3$,two
  • B
    $dsp^2$,zero
  • C
    $dsp^2$,one
  • D
    $sp^3$,one

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The ammine complexes of metal ions $Cu^{2+}$,$Ni^{2+}$ and $Zn^{2+}$ have shapes respectively:

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The number of species from the following that are involved in $sp^3 d^2$ hybridization is $[Co(NH_3)_6]^{3+}, SF_6, [CrF_6]^{3-}, [CoF_6]^{3-}, [Mn(CN)_6]^{3-}$ and $[MnCl_6]^{3-}$.

What is true for $[Fe(CN)_6]^{3-}$ and $[FeF_6]^{3-}$?

Generally,$FeCl_3 \cdot 6H_2O$ is represented as:

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