Misch metal is an alloy of:

In making gun-barrel,the steel used is

Assertion : Solution of $Na_2CrO_4$ in water is intensely coloured.
Reason : Oxidation state of $Cr$ in $Na_2CrO_4$ is $+VI$.

Which compounds are formed when $Mn_2O_7$ and $CrO_3$ react with water,given that they are acidic in nature?

Correct statements from the following are:
$A$. Potassium dichromate is an oxidising agent and it oxidises $FeSO_4$ to $Fe_2(SO_4)_3$ in acidic medium.
$B$. Sodium dichromate can be used as primary standard in volumetric estimation.
$C$. $CrO_4^{2-}$ and $Cr_2O_7^{2-}$ are interconvertible in aqueous solution by varying the $pH$ of the solution.
$D$. $Cr-O-Cr$ bond angle in $Cr_2O_7^{2-}$ is $126^\circ$.
Choose the correct answer from the options given below:

Fusion of $MnO_2$ with $KOH$ in presence of $O_2$ produces a salt $W$. Alkaline solution of $W$ upon electrolytic oxidation yields another salt $X$. The manganese containing ions present in $W$ and $X$,respectively,are $Y$ and $Z$. Correct statement$(s)$ is (are)
$(1)$ $Y$ is diamagnetic in nature while $Z$ is paramagnetic
$(2)$ Both $Y$ and $Z$ are coloured and have tetrahedral shape
$(3)$ In both $Y$ and $Z$,$\pi$-bonding occurs between $p$-orbitals of oxygen and $d$-orbitals of manganese.
$(4)$ In aqueous acidic solution,$Y$ undergoes disproportionation reaction to give $Z$ and $MnO_2$.