Match the reactions given in Column-$I$ with the statements given in Column-$II$.
Column-$I$ Column-$II$ $A$. Ammonolysis $1$. Amine with lesser number of carbon atoms $B$. Gabriel phthalimide synthesis $2$. Detection test for primary amine $C$. Hoffmann Bromamide reaction $3$. Reaction of phthalimide with $KOH$ and $R-X$ $D$. Carbylamine reaction $4$. Reaction of alkyl-halides with $NH_3$
| Column-$I$ | Column-$II$ |
|---|---|
| $A$. Ammonolysis | $1$. Amine with lesser number of carbon atoms |
| $B$. Gabriel phthalimide synthesis | $2$. Detection test for primary amine |
| $C$. Hoffmann Bromamide reaction | $3$. Reaction of phthalimide with $KOH$ and $R-X$ |
| $D$. Carbylamine reaction | $4$. Reaction of alkyl-halides with $NH_3$ |
(A-4, B-3, C-1, D-2) $A-4, B-3, C-1, D-2$
$A$. Ammonolysis: The process of cleavage of the $C-X$ bond by an ammonia molecule is known as ammonolysis. It involves the reaction of alkyl halides with $NH_3$.
$B$. Gabriel phthalimide synthesis: This involves the reaction of phthalimide with $KOH$ followed by reaction with $R-X$ to synthesize primary amines.
$C$. Hoffmann Bromamide reaction: This reaction is used to convert amides to amines with a lesser number of carbon atoms.
$R-CONH_2 + Br_2 + 4NaOH \rightarrow R-NH_2 + Na_2CO_3 + 2NaBr + 2H_2O$
$D$. Carbylamine reaction: This is a specific detection test for primary amines.
$R-NH_2 + CHCl_3 + 3KOH \xrightarrow{\text{Heat}} R-NC + 3KCl + 3H_2O$
$A$. Ammonolysis: The process of cleavage of the $C-X$ bond by an ammonia molecule is known as ammonolysis. It involves the reaction of alkyl halides with $NH_3$.
$B$. Gabriel phthalimide synthesis: This involves the reaction of phthalimide with $KOH$ followed by reaction with $R-X$ to synthesize primary amines.
$C$. Hoffmann Bromamide reaction: This reaction is used to convert amides to amines with a lesser number of carbon atoms.
$R-CONH_2 + Br_2 + 4NaOH \rightarrow R-NH_2 + Na_2CO_3 + 2NaBr + 2H_2O$
$D$. Carbylamine reaction: This is a specific detection test for primary amines.
$R-NH_2 + CHCl_3 + 3KOH \xrightarrow{\text{Heat}} R-NC + 3KCl + 3H_2O$
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