Match the following Column-$I$ (Reaction) with Column-$II$ (colour of the product or nature):

Column-$I$ (Reaction)	Column-$II$ (colour of the product or nature)
$(A)$ $FeCl_3(aq) + NH_3(aq) \rightarrow$	$(I)$ Green ppt
$(B)$ $AgCl(aq) + NH_3(aq) \rightarrow$	$(II)$ Deep blue
	$(III)$ Brown ppt
	$(IV)$ Colourless solution

The correct answer for the sequence $(A, B)$ is:

The correct option(s) about entropy $(S)$ is(are)
$[R =$ gas constant, $F =$ Faraday constant, $T =$ Temperature $]$
$(A)$ For the reaction, $M_{(s)} + 2H^{+}_{(aq)} \rightarrow H_{2(g)} + M^{2+}_{(aq)}$, if $\frac{dE_{cell}}{dT} = \frac{R}{F}$, then the entropy change of the reaction is $R$ (assume that entropy and internal energy changes in entropy and internal energy are temperature independent).
$(B)$ The cell reaction, $Pt_{(s)} \mid H_2(g, 1 \ bar) \mid H^{+}(aq, 0.01 \ M) \parallel H^{+}(aq, 0.1 \ M) \mid H_2(g, 1 \ bar) \mid Pt_{(s)}$, is an entropy driven process.
$(C)$ For racemization of an optically active compound, $\Delta S > 0$.
$(D)$ $\Delta S > 0$, for $[Ni(H_2O)_6]^{2+} + 3en \rightarrow [Ni(en)_3]^{2+} + 6H_2O$ (where $en =$ ethylenediamine).

$A$ mixture $X$ containing $0.02 \, mol$ of $[Co(NH_3)_5SO_4]Br$ and $0.02 \, mol$ of $[Co(NH_3)_5Br]SO_4$ is dissolved in water to make a $2 \, L$ solution.
$1 \, L \, of \, X + \text{Excess of } AgNO_3 \rightarrow Y \, mol \, of \, ppt.$
$1 \, L \, of \, X + \text{Excess of } BaCl_2 \rightarrow Z \, mol \, of \, ppt.$
Then $Y$ and $Z$ are respectively ...............

Match each coordination compound in List-$I$ with an appropriate pair of characteristics from List-$II$ and select the correct answer using the code given below the lists. $\{en = H_2NCH_2CH_2NH_2\}$,atomic numbers:$\{Ti = 22; Cr = 24; Co = 27; Pt = 78\}$

List-$I$	List-$II$
$P$. $[Cr(NH_3)_4Cl_2]Cl$	$1$. Paramagnetic and exhibits ionisation isomerism
$Q$. $[Ti(H_2O)_5Cl](NO_3)_2$	$2$. Diamagnetic and exhibits cis-trans isomerism
$R$. $[Pt(en)(NH_3)Cl]NO_3$	$3$. Paramagnetic and exhibits cis-trans isomerism
$S$. $[Co(NH_3)_4(NO_3)_2]NO_3$	$4$. Diamagnetic and exhibits ionisation isomerism

The volume (in $mL$) of $0.125\; M\; AgNO_{3}$ required to quantitatively precipitate chloride ions in $0.3\; g$ of $[Co(NH_{3})_{6}]Cl_{3}$ is (Given: $M_{[Co(NH_{3})_{6}]Cl_{3}} = 267.46\; g/mol$,$M_{AgNO_{3}} = 169.87\; g/mol$).

Given below are two statements:
Statement $I$: $PF_5$ and $BrF_5$ both exhibit $sp^3 d$ hybridisation.
Statement $II$: Both $SF_6$ and $[Co(NH_3)_6]^{3+}$ exhibit $sp^3 d^2$ hybridisation.
In the light of the above statements,choose the correct answer from the options given below: