Match List-$I$ with List-$II$.
List-$I$:
$(a)$ $\text{Benzene} \xrightarrow[\text{CuCl}]{\text{CO, HCl, Anhyd. AlCl}_3} \text{Benzaldehyde}$
$(b)$ $R-CO-CH_3 + NaOX \rightarrow$
$(c)$ $R-CH_2-OH + R'COOH \xrightarrow{\text{Conc. H}_2\text{SO}_4}$
$(d)$ $R-CH_2COOH \xrightarrow[(ii) H_2O]{(i) X_2/\text{Red P}} R-CH(X)COOH$
List-$II$:
$(i)$ $\text{Hell-Volhard-Zelinsky reaction}$
(ii) $\text{Gattermann-Koch reaction}$
(iii) $\text{Haloform reaction}$
(iv) $\text{Esterification}$
Choose the correct answer from the options given below.

  • A
    $(a)-(iv), (b)-(i), (c)-(ii), (d)-(iii)$
  • B
    $(a)-(iii), (b)-(ii), (c)-(i), (d)-(iv)$
  • C
    $(a)-(i), (b)-(iv), (c)-(iii), (d)-(ii)$
  • D
    $(a)-(ii), (b)-(iii), (c)-(iv), (d)-(i)$

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Match List-$I$ with List-$II$ :
List-$I$ (Chemical Reaction) List-$II$ (Reagent used)
$(a)$ $CH_{3}COOCH_{2}CH_{3} \rightarrow CH_{3}CH_{2}OH$ $(i)$ $CH_{3}MgBr / H_{3}O^{+}$ ($1$ equivalent)
$(b)$ $CH_{3}COOCH_{3} \rightarrow CH_{3}CHO$ $(ii)$ $H_{2}SO_{4} / H_{2}O$
$(c)$ $CH_{3}C \equiv N \rightarrow CH_{3}CHO$ $(iii)$ $DIBAL-H / H_{2}O$
$(d)$ $CH_{3}C \equiv N \rightarrow CH_{3}COCH_{3}$ $(iv)$ $SnCl_{2}, HCl / H_{2}O$

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Arrange the following compounds in increasing order of their property as indicated:
$(i)$ Acetaldehyde,Acetone,Di-tert-butyl ketone,Methyl tert-butyl ketone (reactivity towards $HCN$)
$(ii)$ $CH_3CH_2CH(Br)COOH$,$CH_3CH(Br)CH_2COOH$,$(CH_3)_2CHCOOH$,$CH_3CH_2CH_2COOH$ (acid strength)
$(iii)$ Benzoic acid,$4$-Nitrobenzoic acid,$3,4$-Dinitrobenzoic acid,$4$-Methoxybenzoic acid (acid strength)

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The correct order of acidity for the following compounds is:

The product $(X)$ of the reaction is:

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When compound $X$ is oxidised by acidified potassium dichromate,compound $Y$ is formed. Compound $Y$ on reduction with $LiAlH_4$ gives $X$. $X$ and $Y$ respectively are:

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