In which of the following reactions is an aromatic aldehyde treated with an acid anhydride in the presence of the corresponding salt of the acid to give an unsaturated aromatic acid?

A closed tank has two compartments $A$ and $B$, both filled with oxygen (assumed to be ideal gas). The partition separating the two compartments is fixed and is a perfect heat insulator (Figure $1$). If the old partition is replaced by a new partition which can slide and conduct heat but does $NOT$ allow the gas to leak across (Figure $2$), the volume (in $m ^3$ ) of the compartment $A$ after the system attains equilibrium is. . . . . .