In which of the following reactions is there no change in the valency (oxidation state) of the elements?

  • A
    $4KClO_3 \to 3KClO_4 + KCl$
  • B
    $SO_2 + 2H_2S \to 2H_2O + 3S$
  • C
    $BaO_2 + H_2SO_4 \to BaSO_4 + H_2O_2$
  • D
    $2BaO + O_2 \to 2BaO_2$

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Balance the following equations in basic medium by the ion-electron method and identify the oxidising agent and the reducing agent.
$(a)$ $P_{4(s)} + OH^{-}_{(aq)} \rightarrow PH_{3(g)} + H_{2}P{O_{2}}^{-}_{(aq)}$
$(b)$ $N_{2}H_{4(l)} + Cl{O_{3}}^{-}_{(aq)} \rightarrow NO_{(g)} + Cl^{-}_{(g)}$
$(c)$ $Cl_{2}O_{7(g)} + H_{2}O_{2(aq)} \rightarrow Cl{O_{2}}^{-}_{(aq)} + O_{2(g)} + H^{+}_{(aq)}$

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