In which of the following plots,an endothermic reaction is correctly represented?

At $400 \ K$,in a $1.0 \ L$ vessel,$N_2O_4$ is allowed to attain equilibrium,$N_2O_{4(g)} \rightleftharpoons 2NO_{2(g)}$. At equilibrium,the total pressure is $600 \ mm \ Hg$,when $20 \%$ of $N_2O_4$ is dissociated. The value of $K_p$ for the reaction is

The half-life of forward and reverse reactions are $400 \, sec$ and $100 \, sec$ respectively. If these half-lives are independent of the concentration of the reactant,find the equilibrium constant of the reaction.

In the reaction $PCl_5 \rightleftharpoons PCl_3 + Cl_2$,the partial pressures of $PCl_3$,$Cl_2$,and $PCl_5$ are $0.3 \ atm$,$0.2 \ atm$,and $0.6 \ atm$ respectively. If the partial pressures of $PCl_3$ and $Cl_2$ are doubled,what will be the partial pressure of $PCl_5$ in $atm$?

At $T(K)$,the following gaseous equilibrium is established: $W + X \rightleftharpoons Y + Z$. The initial concentration of $W$ is two times the initial concentration of $X$. The system is heated to $T(K)$ to establish equilibrium. At equilibrium,the concentration of $Y$ is four times the concentration of $X$. What is the value of $K_c$?

For the following gas phase equilibrium reaction at constant temperature,$NH_{3(g)} \rightleftharpoons \frac{1}{2} N_{2(g)} + \frac{3}{2} H_{2(g)}$. If the total pressure is $\sqrt{3} \ atm$ and the pressure equilibrium constant $(K_p)$ is $9 \ atm$,then the degree of dissociation is given as $(x \times 10^{-2})^{-1/2}$. The value of $x$ is . . . . . . (Nearest integer)