In which of the following conversions does a blue colour appear?

Identify the substance oxidised,reduced,oxidising agent,and reducing agent for each of the following reactions:
$(a)$ $2 AgBr_{(s)} + C_6 H_6 O_{2(aq)} \rightarrow 2 Ag_{(s)} + 2 HBr_{(aq)} + C_6 H_4 O_{2(aq)}$
$(b)$ $HCHO_{(l)} + 2 [Ag(NH_3)_2]^+_{(aq)} + 3 OH^-_{(aq)}$ $\rightarrow 2 Ag_{(s)} + HCOO^-_{(aq)} + 4 NH_{3(aq)} + 2 H_2 O_{(l)}$
$(c)$ $HCHO_{(l)} + 2 Cu^{2+}_{(aq)} + 5 OH^-_{(aq)} \rightarrow Cu_2 O_{(s)} + HCOO^-_{(aq)} + 3 H_2 O_{(l)}$
$(d)$ $N_2 H_{4(l)} + 2 H_2 O_{2(l)} \rightarrow N_{2(g)} + 4 H_2 O_{(l)}$
$(e)$ $Pb_{(s)} + PbO_{2(s)} + 2 H_2 SO_{4(aq)} \rightarrow 2 PbSO_{4(s)} + 2 H_2 O_{(l)}$

Assign $A, B, C, D$ from the given type of reaction.
$2KI + HgI_2 \downarrow \longrightarrow K_2[HgI_4]$

Balance the following redox reactions using the oxidation number and ion-electron method:
$(1) \ Zn + NO_3^- + H^+ \to Zn^{2+} + N_2O + H_2O$
$(2) \ I^- + O_2 + H_2O \to I_2 + OH^-$
$(3) \ MnO_4^- + C_2H_5OH \to Mn^{2+} + CH_3COOH$

Match the following columns:-

Column-$I$ [Type of reaction]	Column-$II$ [Example]
$I$. Intermolecular redox reaction	$A$. $CH_4 + 2O_2 \rightarrow CO_2 + 2H_2O$
$II$. Intramolecular redox reaction	$B$. $NH_4NO_2 \rightarrow N_2 + 2H_2O$
$III$. Disproportionation reaction	$C$. $2H_2O_2 \rightarrow 2H_2O + O_2$
$IV$. Comproportionation reaction	$D$. $KClO_3 \rightarrow KCl + \frac{3}{2}O_2$

Which of the following reactants can be reduced by $SO_2$ in the given reactions?
$(I)$ $O_3 \to$ product
$(II)$ $Cr_2O_7^{2-} \xrightarrow{H^{+}} $ product
$(III)$ $MnO_4^{-} \xrightarrow{H^{+}} $ product
$(IV)$ $H_2S \to$ product