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In the reaction sequence $CH_3Cl$ $\xrightarrow{KCN}$ $\xrightarrow{+4H} A$ $\xrightarrow{NaNO_2/HCl} \text{Ethyl alcohol} + ?$. What are the major and minor products formed?

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$CH_3NO_2 \xrightarrow{Sn + HCl} CH_3X$,the '$X$' contains:

The following sequence of reactions on $A$ gives:

The major product in the following reaction at $25^{\circ} C$ is $CH_3COOH \xrightarrow{CH_3CH_2NH_2}$

The correct order of basicity for the following molecules is $:$

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