In the nitroprusside ion,the iron exists as $Fe^{2+}$ and $NO$ as $NO^{+}$ rather than $Fe^{3+}$ and $NO$ respectively. These forms of ions are established with the help of
- Amagnetic moment in solid state
- Bthermal decomposition method
- Cby reaction with $KCN$
- Dby action with $K_2SO_4$
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