In Dumas's method for estimation of nitrogen,$0.25 \, g$ of an organic compound gave $40 \, mL$ of nitrogen collected at $300 \, K$ temperature and $725 \, mm$ pressure. If the aqueous tension at $300 \, K$ is $25 \, mm,$ the percentage of nitrogen in the compound is

$A$ sample of $0.125 \ g$ of an organic compound when analysed by Duma's method yields $22.78 \ mL$ of nitrogen gas collected over $KOH$ solution at $280 \ K$ and $759 \ mm \ Hg$. The percentage of nitrogen in the given organic compound is (Nearest integer).
$(a)$ The vapour pressure of water at $280 \ K$ is $14.2 \ mm \ Hg$
$(b)$ $R = 0.082 \ L \ atm \ K^{-1} \ mol^{-1}$

Differentiate between the principle of estimation of nitrogen in an organic compound by $(i)$ Dumas method and $(ii)$ Kjeldahl's method.

An organic compound is subjected to chlorination to get compound $A$. When $0.5 \ g$ of compound $A$ is reacted with $AgNO_3$ [Carius Method],it forms $0.3849 \ g$ of $AgCl$. Calculate the percentage of chlorine in compound $A$. (Round off to the nearest integer)
(Atomic masses of $Ag$ and $Cl$ are $107.87$ and $35.5$ respectively)

Explain the Carius method and its principle for the estimation of phosphorus in an organic compound.

In the estimation of $C$ and $H$ by Liebig's method,is $H_2O$ absorbed before $CO_2$? Why?