In Dumas' method for estimation of nitrogen,$0.3 \ g$ of an organic compound gave $50 \ mL$ of nitrogen collected at $300 \ K$ temperature and $715 \ mm$ pressure. Calculate the percentage composition of nitrogen in the compound. (Aqueous tension at $300 \ K = 15 \ mm$)

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) The pressure of dry nitrogen is $P_{N_2} = P_{total} - P_{aqueous} = 715 \ mm - 15 \ mm = 700 \ mm$.
Using the combined gas law to convert the volume to $STP$ ($273 \ K$ and $760 \ mm$):
$V_{STP} = \frac{P_{N_2} \times V \times 273}{P_{STP} \times T} = \frac{700 \times 50 \times 273}{760 \times 300} \approx 41.91 \ mL$.
Since $22,400 \ mL$ of $N_2$ at $STP$ weighs $28 \ g$,the mass of $N_2$ is:
$Mass_{N_2} = \frac{28 \times 41.91}{22400} \approx 0.05239 \ g$.
Percentage of nitrogen $= \frac{Mass_{N_2}}{Mass_{compound}} \times 100 = \frac{0.05239}{0.3} \times 100 \approx 17.46 \%$.

Explore More

Similar Questions

State whether the following statements are True or False:
$(i)$ The estimation of sulphur is detected by the weight of $BaSO_4$.
$(ii)$ $BaCl_2$ is added in the estimation of sulphur.
$(iii)$ The Carius tube is used in the estimation of sulphur.
$(iv)$ The magnesium mixture is added in the estimation of sulphur.

When $1 \ g$ of compound $(X)$ is subjected to Kjeldahl's method for the estimation of nitrogen,$15 \ mL$ of $1 \ M$ $H_2SO_4$ was neutralized by the ammonia evolved. The percentage of nitrogen in compound $(X)$ is:

Which compounds are taken in the Kjeldahl's flask for the estimation of nitrogen?

In an estimation of sulphur by Carius method,$0.2 \text{ g}$ of the substance gave $0.6 \text{ g}$ of $BaSO_4$. The percentage of sulphur in the substance is . . . . . . %. (Given molar mass in $\text{g mol}^{-1}$: $S = 32$,$BaSO_4 = 233$)

In Carius method for estimation of halogens,$0.2 \, g$ of an organic compound gave $0.188 \, g$ of $AgBr$. The percentage of bromine in the compound is $......$ . (Nearest integer)
[Atomic mass: $Ag=108, Br=80$ ]

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo