In a set of reactions,p-nitrotoluene yielded | vedclass

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(C) $1$. The starting material is $p$-nitrotoluene. $2$. Electrophilic aromatic substitution with $Br_2/FeBr_3$ introduces a bromine atom at the ortho

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$2,4-$dibromotoluene

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(C) $1$. The starting material is $p$-nitrotoluene. $2$. Electrophilic aromatic substitution with $Br_2/FeBr_3$ introduces a bromine atom at the ortho position relative to the methyl group (since the $-CH_3$ group is ortho/para directing and the $-NO_2$ group is meta directing). This gives $B$ as $2$-bromo-$4$-nitrotoluene. $3$. Reduction of the nitro group with $Sn/HCl$ converts the $-NO_2$ group to an $-NH_2$ group,yielding $C$ ($2$-bromo-$4$-aminotoluene). $4$. Diazotization with $NaNO_2/HCl$ at $0-5 \ ^\circ C$ converts the $-NH_2$ group into a diazonium salt,$D$ ($2$-bromo-$4$-methylbenzenediazonium chloride). $5$. The Sandmeyer reaction with $CuBr/HBr$ replaces the diazonium group with a bromine atom,resulting in $E$ ($2,4$-dibromotoluene).

Column-$I$ (Reactants)	Column-$II$ (Products)
$(A)$ $p$-Nitrochlorobenzene $\xrightarrow[(ii) H^+]{(i) NaOH, 443 \ K}$	$(i)$ Phenol
$(B)$ Chlorobenzene $\xrightarrow[(ii) H^+]{(i) NaOH, 623 \ K, 300 \ atm}$	$(ii)$ $2,4,6$-Trinitrophenol
$(C)$ $2,4$-Dinitrochlorobenzene $\xrightarrow[(ii) H^+]{(i) NaOH, 368 \ K}$	$(iii)$ $2,4$-Dinitrophenol
$(D)$ $2,4,6$-Trinitrochlorobenzene $\xrightarrow{Warm \ H_2O}$	$(iv)$ $p$-Nitrophenol

In a set of reactions,$p$-nitrotoluene yielded a product $E$. The product $E$ would be:
$p$-nitrotoluene $\xrightarrow[FeBr_3]{Br_2} B$ $\xrightarrow{Sn/HCl} C$ $\xrightarrow[HCl]{NaNO_2} D$ $\xrightarrow[HBr]{CuBr} E$

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In a set of reactions,$p$-nitrotoluene yielded a product $E$. The product $E$ would be:$p$-nitrotoluene $\xrightarrow[FeBr_3]{Br_2} B$ $\xrightarrow{Sn/HCl} C$ $\xrightarrow[HCl]{NaNO_2} D$ $\xrightarrow[HBr]{CuBr} E$