If the magnetic moment of a dioxygen species is $1.73 \;B.M$, it may be

Give answer of following questions.

$(i)$ Give molecular orbitals and type form by $\mathrm{LCAO}$ from $2{\rm{s}},2{{\rm{p}}_{\rm{x}}},2{{\rm{p}}_{\rm{y}}}$ and $2{{\rm{p}}_{\rm{z}}}$ 

$(ii)$ ${\rm{L}}{{\rm{i}}_2},{\rm{B}}{{\rm{e}}_2},{{\rm{C}}_2},{{\rm{N}}_2},{{\rm{O}}_2}{\rm{,}}{{\rm{F}}_2}$ for these molecule give energy other.

Among $\mathrm{H}_2, \mathrm{He}_2^{+}, \mathrm{Li}_2, \mathrm{Be}_2, \mathrm{~B}_2, \mathrm{C}_2, \mathrm{~N}_2, \mathrm{O}_2^{-}$, and $\mathrm{F}_2$, the number of diamagnetic species is (Atomic numbers: $\mathrm{H}=1, \mathrm{He}=2, \mathrm{Li}=3, \mathrm{Be}=4, \mathrm{~B}=5, \mathrm{C}=6, \mathrm{~N}=7, \mathrm{O}=8, \mathrm{~F}=9$ )

Explain energy level diagram for molecular orbital form by $1\mathrm{s}$ orbitals.

Correct decreasing order of bond order of oxygen species in $I$ to $IV$

$(I)$   $Na_2O_2$

$(II)$  $O_2 [AsF_6]$

$(III)$  $CsO_2$

$(IV)$  $O_2$

Compare the relative stability of the following species and indicate their magnetic properties;

$O _{2}, O _{2}^{+}, O _{2}^{-}$ (superoxide), $O _{2}^{2-}$ (peroxide)