Identify the pair of complexes that exhibits | vedclass

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Question

(A) Solvate isomerism (also known as hydrate isomerism when water is the solvent) occurs when the solvent molecule acts as a ligand in one isomer and

Vedclass · Accepted Answer

$[Cr(H_2O)_6]Cl_3$ and $[Cr(H_2O)_5Cl]Cl_2 \cdot H_2O$

Vedclass · Answer

(A) Solvate isomerism (also known as hydrate isomerism when water is the solvent) occurs when the solvent molecule acts as a ligand in one isomer and as a lattice molecule (outside the coordination sphere) in another.In the pair $[Cr(H_2O)_6]Cl_3$ and $[Cr(H_2O)_5Cl]Cl_2 \cdot H_2O$,the first complex has $6$ water molecules as ligands,while the second has $5$ water molecules as ligands and $1$ water molecule as a lattice molecule.Therefore,this pair exhibits solvate isomerism.

Identify the pair of complexes that exhibits solvate isomerism.

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