How can an electrochemical cell be converted into an electrolytic cell?

  • A
    Applying an external opposite potential greater than $E_{\text{cell}}^0$
  • B
    Reversing the flow of ions in salt bridge.
  • C
    Applying an external opposite potential lower than $E_{\text{cell}}^0$.
  • D
    Exchanging the electrodes at anode and cathode.

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For the cell $Cu_{(s)} | Cu^{2+}_{(aq)} (1 \ M) || Zn^{2+}_{(aq)} (1 \ M) | Zn_{(s)}$,given $E^{\circ}_{Zn^{2+}/Zn} = -0.76 \ V$ and $E^{\circ}_{Cu^{2+}/Cu} = 0.34 \ V$,the cell reaction is:

Depict the galvanic cell in which the reaction $Zn_{(s)} + 2Ag^{+}_{(aq)} \rightarrow Zn^{2+}_{(aq)} + 2Ag_{(s)}$ takes place. Further show:
$(i)$ Which of the electrode is negatively charged?
$(ii)$ The carriers of the current in the cell.
$(iii)$ Individual reaction at each electrode.

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Which substance is used as cathode in a mercury cell?

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