Given $E_{Fe^{3+}/Fe^{2+}}^{\circ} = +0.76 \ V$ and $E_{I_{2}/I^{-}}^{\circ} = +0.55 \ V$. The equilibrium constant for the reaction taking place in a galvanic cell consisting of the above two electrodes is (Given $\frac{2.303 \ RT}{F} = 0.06 \ V$)

  • A
    $1 \times 10^{7}$
  • B
    $1 \times 10^{9}$
  • C
    $3 \times 10^{8}$
  • D
    $5 \times 10^{12}$

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Which of the following statements is $NOT$ correct?

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During the discharging of a lead storage cell,the concentration of $H_2SO_4$ reduces from $40\% \ w/w$ to $30\% \ w/w$. Find the total charge produced in $faraday$. Given the volume of the solution $= 4.9 \ L$ and density $= 1.2 \ g/mL$. (Assume volume and density remain constant)

The standard reduction potentials of $2H^{+}/H_2$,$Cu^{2+}/Cu$,$Zn^{2+}/Zn$,and $NO_3^{-}, H^{+}/NO$ are $0.0 \ V$,$0.34 \ V$,$-0.76 \ V$,and $0.97 \ V$ respectively. Observe the following reactions:
$I$. $Zn + HCl \rightarrow$
$II$. $Cu + HCl \rightarrow$
$III$. $Cu + HNO_3 \rightarrow$
Which reactions do not liberate $H_{2(g)}$?

Consider an electrochemical cell: $A_{(s)} | A^{n+}(aq, 2 \ M) || B^{2n+}(aq, 1 \ M) | B_{(s)}$. The value of $\Delta H^{\ominus}$ for the cell reaction is twice that of $\Delta G^{\ominus}$ at $300 \ K$. If the emf of the cell is zero,the $\Delta S^{\ominus}$ (in $J \ K^{-1} \ mol^{-1}$) of the cell reaction per mole of $B$ formed at $300 \ K$ is. . . . . . . (Given: $\ln(2) = 0.7, R = 8.3 \ J \ K^{-1} \ mol^{-1}$.)

Match the following:
List-$I$List-$II$
$(A)$ Potential of hydrogen electrode at $pH = 10$$(I)$ $0.76 \ V$
$(B)$ $Cu^{2+}|Cu$$(II)$ $0.059$
$(C)$ $Zn|Zn^{2+}$$(III)$ $-0.591 \ V$
$(D)$ $\frac{2.303RT}{F}$$(IV)$ $0.337 \ V$
$(V)$ $-0.76 \ V$

$(a)$ $A-III, B-I, C-II, D-V$
$(b)$ $A-II, B-V, C-I, D-IV$
$(c)$ $A-III, B-IV, C-I, D-II$
$(d)$ $A-V, B-I, C-IV, D-II$

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