Give the difference between intermolecular hydrogen bond and intramolecular hydrogen bond.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(A) The differences between intermolecular and intramolecular hydrogen bonds are as follows:
| Feature | Intermolecular Hydrogen Bond | Intramolecular Hydrogen Bond |
| :--- | :--- | :--- |
| Definition | It is formed between two different molecules of the same or different compounds. | It is formed when a hydrogen atom is between two highly electronegative atoms present within the same molecule. |
| Example | Liquid $HF$ | $o$-Nitrophenol |
| Effect on physical properties | It increases the boiling point and melting point of the substance. | It has a lesser effect on physical properties compared to intermolecular hydrogen bonding. |
| Structural aspect | It leads to association of molecules. | It leads to chelation (ring formation) within the molecule. |

Explore More

Similar Questions

Which of the following bonds is responsible for the maximum value of hydrogen bonding?

How many water molecules present in $CuSO_4 \cdot 5 H_2 O$ are hydrogen bonded?

Assertion : Boiling point of $p$-nitrophenol is higher than that of $o$-nitrophenol.
Reason : $p$-nitrophenol has intermolecular hydrogen bond whereas $o$-nitrophenol has intramolecular hydrogen bond.

Which one of the following does not have intermolecular hydrogen bonding?

Given below are two statements: one is labelled as Assertion $A$ and the other is labelled as Reason $R$.
Assertion $A$: Dipole-dipole interactions are the only non-covalent interactions resulting in hydrogen bond formation.
Reason $R$: Fluorine is the most electronegative element and hydrogen bonds in $HF$ are symmetrical.

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo