From the following thermochemical equations,find out the heat of ionisation $Z$ for a weak acid $HA$:
$HA \to A^{-} + H^{+} , \Delta H = Z$
$H^{+} + OH^{-} \to H_2O , \Delta H = X$
$HA + OH^{-} \to A^{-} + H_2O , \Delta H = Y$

The standard heats of formation in $kcal \ mol^{-1}$ of $NO_{2(g)}$ and $N_2O_{4(g)}$ are $8.0$ and $2.0$ respectively. The heat of dimerization of $NO_2$ in $kcal$ for the reaction $2NO_{2(g)} \rightarrow N_2O_{4(g)}$ is:

Comment on the thermodynamic stability of $NO_{(g)}$,given:
$\frac{1}{2} N_{2(g)} + \frac{1}{2} O_{2(g)} \rightarrow NO_{(g)}; \Delta_r H^{\ominus} = 90 \, kJ \, mol^{-1}$
$NO_{(g)} + \frac{1}{2} O_{2(g)} \rightarrow NO_{2(g)}; \Delta_r H^{\ominus} = -74 \, kJ \, mol^{-1}$

Based on the values of $B.E.$ given,calculate the $\Delta_fH^o$ of $N_2H_4\, (g)$ in $kJ\, mol^{-1}$.
Given : $N-N = 159\, kJ\, mol^{-1};\, H-H = 436\, kJ\, mol^{-1}$
$N \equiv N = 941\, kJ\, mol^{-1};\, N-H = 398\, kJ\, mol^{-1}$

If the standard molar enthalpy change for combustion of graphite powder is $-2.48 \times 10^{2} \ kJ \ mol^{-1}$,the amount of heat generated on combustion of $1 \ g$ of graphite powder is $..... \ kJ$.
(Nearest integer)

If the enthalpy of neutralization of $HCN$ and $NaOH$ is $-12.13 \, kJ/mol$,then the enthalpy of ionization of $HCN$ will be ...... $kJ/mol$.