The formula of nickel oxide with metal deficiency defect in its crystal is $Ni_{0.98}O$. The crystal contains $Ni^{2+}$ and $Ni^{3+}$ ions. The fraction of nickel existing as $Ni^{2+}$ ions in the crystal is

Which of the following statements is correct?

$KBr$ is doped with $10^{-5}$ mole percent of $SrBr_2$. The number of cationic vacancies in $1 \ g$ of $KBr$ crystal is ........ $\times 10^{14}$. (Round off to the Nearest Integer).
[Atomic Mass : $K = 39.1 \ u$,$Br = 79.9 \ u$; $N_A = 6.023 \times 10^{23} \ mol^{-1}$]

It is observed that $Li_2O$ is soluble in $NiO$ in small amounts,where $Li^+$ ions occupy some of the cation sites. Which of the following conclusions can be drawn?

Explain the following term with a suitable example:
$(ii)$ Frenkel defect

$A$ sample of ferrous oxide has actual formula $Fe_{0.93}O_{1.00}$. In this sample,what fraction of metal ions are $Fe^{2+}$ ions? What type of non-stoichiometric defect is present in this sample?