For the transformation shown below,the reagent used is:

What is the expected order of basic strength of different compounds from the following in the aqueous phase?

Given below are two statements :
Statement $I$: Aniline reacts with conc. $H_2SO_4$ followed by heating at $453-473 \ K$ to give $p$-aminobenzene sulphonic acid (sulphanilic acid). This compound contains both nitrogen and sulphur,and thus it gives a blood red colour in the 'Lassaigne's test' due to the formation of ferric thiocyanate,$[Fe(SCN)]^{2+}$.
Statement $II$: In Friedel-Craft's alkylation and acylation reactions,aniline forms a salt with the $AlCl_3$ catalyst. Due to this,the nitrogen atom of aniline acquires a positive charge and acts as a deactivating group,preventing further reaction.
In the light of the above statements,choose the correct answer from the options given below :

Azo-dyes are prepared from:

By reduction of nitrosobenzene,which of the following is not obtained?

What is the physical state of pure aniline?