For the reaction,$N_2O_{4(g)} \rightleftharpoons 2NO_{2(g)}$,if dinitrogen tetroxide is $50\%$ dissociated at $60^\circ C$,the standard free energy change at this temperature and $1 \ atm$ pressure is:

  • A
    $-367.8 \ J \ mol^{-1}$
  • B
    $-763.8 \ J \ mol^{-1}$
  • C
    $-867 \ J \ mol^{-1}$
  • D
    $-249 \ J \ mol^{-1}$

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In a $1.0 \, L$ vessel at $90 \, ^\circ C$,$0.2 \, mol$ of $H_{2(g)}$ and $2.0 \, mol$ of $S_{(s)}$ are mixed. For the reaction $H_{2(g)} + S_{(s)} \rightleftharpoons H_2S_{(g)}$; $K_p = 6.8 \times 10^{-2}$,the partial pressure of $H_2S_{(g)}$ at equilibrium will be ............ $atm$.

At $783 \, K$ in the reaction,$H_{2(g)} + I_{2(g)} \rightleftharpoons 2 HI_{(g)}$,the molar concentrations $(mol \, L^{-1})$ of $H_2, I_2$ and $HI$ at some instant of time are $0.1, 0.2$ and $0.4$,respectively. If the equilibrium constant is $46$ at the same temperature,then as the reaction proceeds:

For the reactions $X \rightleftharpoons 2Y$ and $Z \rightleftharpoons P + Q$,the equilibrium constants $K_p$ and $K_q$ are in the ratio $1:9$. If the degree of dissociation of $X$ and $Z$ is the same,then the ratio of their total pressures is:

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The number of correct statement$(s)$ involving equilibria in physical processes from the following is:
$A$. Equilibrium is possible only in a closed system at a given temperature.
$B$. Both the opposing processes occur at the same rate.
$C$. When equilibrium is attained at a given temperature,the value of all its parameters becomes constant.
$D$. For dissolution of solids in liquids,the solubility is constant at a given temperature.

$A$ $1 \, M$ solution of glucose reaches dissociation equilibrium according to the equation $C_6H_{12}O_6 \rightleftharpoons 6HCHO$. What is the concentration of $HCHO$ at equilibrium if the equilibrium constant $K_c$ for the formation of glucose from formaldehyde is $6 \times 10^{22}$?

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