For the reaction,$3 C_2 H_{2(g)} \longrightarrow C_6 H_{6(g)}$,calculate the standard enthalpy change. The values of $\Delta H_f$ for $C_2 H_2$ and $C_6 H_6$ respectively are $250 \ kJ \ mol^{-1}$ and $90 \ kJ \ mol^{-1}$.

Which among the following represents the reaction of formation of the product?

Molar enthalpy of combustion of $C_2H_{2(g)}$,$C_{(s)}$,and $H_{2(g)}$ are $-1300$,$-394$,and $-286 \ kJ/mol$ respectively. The standard enthalpy of formation of $C_2H_{2(g)}$ is $:$

For the reaction $C_{2}H_{6} \rightarrow C_{2}H_{4} + H_{2}$,the reaction enthalpy $\Delta_{r}H = \dots \dots \dots \dots \dots \dots \dots \dots \dots \dots \dots \dots \, kJ \, mol^{-1}$. (Round off to the Nearest Integer). [Given: Bond enthalpies in $kJ \, mol^{-1} : C-C : 347, C=C : 611, C-H : 414, H-H : 436$]

The heat of combustion of carbon to $CO_2$ is $-393.5 \ kJ/mol$. The heat released upon formation of $35.2 \ g$ of $CO_2$ from carbon and oxygen gas is

$H_2 + Cl_2 \longrightarrow 2HCl$ ; $\Delta H = -x \ kJ$
$NaCl + H_2SO_4 \longrightarrow NaHSO_4 + HCl$ ; $\Delta H = -y \ kJ$
$2H_2O + 2Cl_2 \longrightarrow 4HCl + O_2$ ; $\Delta H = -z \ kJ$
From the above equations,the value of $\Delta H_f$ of $HCl$ is: