For the reaction,$2 CO + O_2 \longrightarrow 2 CO_2$; $\Delta H = -560 \ kJ$. Two moles of $CO$ and one mole of $O_2$ are taken in a container of volume $1 \ L$. They completely form two moles of $CO_2$. The gases deviate appreciably from ideal behavior. If the pressure in the vessel changes from $70 \ atm$ to $40 \ atm$,find the magnitude (absolute value) of $\Delta U$ at $500 \ K$. $(1 \ L \ atm = 0.1 \ kJ)$

  • A
    $557$
  • B
    $478$
  • C
    $654$
  • D
    $324$

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Similar Questions

For an endothermic reaction where $\Delta H$ represents the enthalpy of the reaction in $kJ/mole$,the minimum value for the energy of activation $(E_a)$ will be:

Identify the incorrect statements among the following:
$(a)$ All enthalpies of fusion are positive.
$(b)$ The magnitude of enthalpy change does not depend on the strength of the intermolecular interactions in the substance undergoing phase transformations.
$(c)$ When a chemical reaction is reversed,the value of $\Delta_r H^{\circ}$ is reversed in sign.
$(d)$ The change in enthalpy is dependent on the path between the initial state (reactants) and final state (products).
$(e)$ For most of the ionic compounds,$\Delta_{\text{sol}} H^{\circ}$ is negative.

For the reaction $H_{2}O_{(l)} \rightleftharpoons H_{2}O_{(g)}$ at $373 \ K$ and $1 \ atm$ pressure:

$CsOH + HCl \to CsCl + H_2O$,$\Delta H = -13.4 \ K \ cal/mol$
$CsOH + HA \to CsA + H_2O$,$\Delta H = -10.4 \ K \ cal/mol$
Then calculate $\Delta H$ of ionisation of $HA$ in $K \ cal/mol$.

For the process $H_2O_{(l)} (1 \ bar, 373 \ K) \rightarrow H_2O_{(g)} (1 \ bar, 373 \ K)$,the correct set of thermodynamic parameters is:

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