For the first order reaction $2 N_2O_{5(g)} \rightarrow 4 NO_{2(g)} + O_{2(g)}$,which of the following statements are correct?
$A.$ The concentration of the reactant decreases exponentially with time.
$B.$ The half-life of the reaction decreases with increasing temperature.
$C.$ The half-life of the reaction depends on the initial concentration of the reactant.
$D.$ The reaction proceeds to $99.6 \%$ completion in eight half-life durations.

  • A
    $A, B, D$
  • B
    $A, B, C$
  • C
    $A, C, D$
  • D
    $B, C, D$

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Given below are two statements:
Statement $I$: The graph of $t_{1/2}$ versus initial concentration $[R]_0$ for a first-order reaction is a horizontal line.
Statement $II$: The graph of $\log \frac{[R]_0}{[R]}$ versus time $t$ for a first-order reaction is a straight line passing through the origin with a slope equal to $\frac{k}{2.303}$.
In the light of the above statements,choose the correct answer from the options given below:

The rate constant $k$,for the reaction ${N_2}{O_5}_{(g)} \to 2N{O_2}_{(g)} + \frac{1}{2}{O_2}_{(g)}$ is $2.3 \times 10^{-2} \ s^{-1}$. Which equation given below describes the change of $[{N_2}{O_5}]$ with time? $[{N_2}{O_5}]_0$ and $[{N_2}{O_5}]_t$ correspond to concentration of ${N_2}{O_5}$ initially and at time $t$.

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