For the equilibrium $H_2O_{(l)} \rightleftharpoons H_2O_{(g)}$ at $1 \ atm$ and $298 \ K$,which of the following statements is correct?

Solid $KClO_4$ is taken in a container maintained at a constant pressure of $1 \, atm$. Upon heating,the following equilibrium is obtained:
$2KClO_{4(s)} \rightleftharpoons 2KCl_{(s)} + 3O_{2(g)}$
If $\Delta H^o = 25 \, kcal/mol$ and $\Delta S^o = 50 \, cal/K \cdot mol$,at what temperature will equilibrium be established in the container (in $, K$)? (Ignore variation of $\Delta H^o$ and $\Delta S^o$ with temperature.)

The equilibrium constant of the following given reaction is $K_p = 6.022 \times 10^{-5}$ at $298 \ K$ temperature. $PCl_{5(g)} \rightleftharpoons PCl_{3(g)} + Cl_{2(g)}$. Calculate the value of $\Delta_r G^o$.

For a homogeneous gaseous reaction,the equilibrium constant $K_p$ is $10^{-8}$. The standard Gibbs free energy change for the reaction is ........... $kcal$. $(R = 2.0 \, cal \, K^{-1} \, mol^{-1}, T = 298 \, K)$

Which condition among the following holds true at the state of half-completion for the reaction $A \rightleftharpoons B$?

If $\Delta_fG^o [X_{(l)}] = -65 \, kcal \, mol^{-1}$ and $\Delta_fG^o [X_{(g)}] = -60.4 \, kcal \, mol^{-1},$ the vapour pressure of $X$ at $500 \, K$ would be about ...... $atm$.
Given: $R = 2 \, cal \, K^{-1} \, mol^{-1}$,$\ln \, a = 2.3 \, \log \, a$.