For a reaction taking place in a container in equilibrium with its surroundings,the effect of temperature on its equilibrium constant $K$ in terms of change in entropy is described by:

  • A
    $[A]$ With increase in temperature,the value of $K$ for exothermic reaction decreases because entropy change of the system is positive
  • B
    $[B]$ With increase in temperature,the value of $K$ for endothermic reaction increases because unfavourable change in entropy of the surroundings decreases
  • C
    $[C]$ With increase in temperature,the value of $K$ for endothermic reaction increases because the entropy change of the system is negative
  • D
    $[D]$ With increase in temperature,the value of $K$ for exothermic reaction decreases because favourable change in entropy of the surrounding decreases

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One mole each of $He$ and $A(g)$ are taken in a $10 \text{ L}$ closed flask and heated to $400 \text{ K}$ to establish the following equilibrium: $A(g) \rightleftharpoons B(g)$. $K_{c}$ for this reaction at $400 \text{ K}$ is $4.0$. The partial pressures (in $\text{atm}$) of $He$ and $B(g)$ are respectively (at equilibrium) (Assume $He$,$A(g)$ and $B(g)$ behave as ideal gases) (Given: $R = 0.082 \text{ L atm K}^{-1} \text{ mol}^{-1}$)

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