Explain the structures of diborane and boric acid.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) $B_2H_6$ is an electron-deficient compound. It has only $12$ valence electrons: $6$ from $6$ $H$ atoms and $3$ each from $2$ $B$ atoms. Thus,after forming $3$ terminal $B-H$ bonds,the boron atoms have no electrons left for bridging. $X$-ray diffraction studies reveal the structure of diborane:
$1$. Two boron and four terminal hydrogen atoms $(H_t)$ lie in one plane.
$2$. The two bridging hydrogen atoms $(H_b)$ lie in a plane perpendicular to the plane of the boron atoms,one above and one below.
$3$. The terminal bonds are regular two-centre two-electron $(2c-2e^-)$ bonds.
$4$. The two bridging $(B-H-B)$ bonds are three-centre two-electron $(3c-2e^-)$ bonds,often called banana bonds.
Boric acid $(H_3BO_3)$:
Boric acid has a layered structure. Each planar $BO_3^{3-}$ unit is linked to others through hydrogen bonds. The $H$ atoms form a covalent bond with oxygen in one $BO_3$ unit,while forming a hydrogen bond with oxygen in another $BO_3$ unit. The dotted lines in the structure represent these hydrogen bonds.

Explore More

Similar Questions

The $pH$ value of which one of the following is not equal to $1$?

If $\sin ^{-1} x+\sin ^{-1}(1-x)=\cos ^{-1} x$,then $x \in$

Suppose $X$ follows a binomial distribution with parameters $n$ and $p$,where $0 < p < 1$. If $\frac{P(X=r)}{P(X=n-r)}$ is independent of $n$ for every $r$,then $p$ is equal to

The energy required to accelerate a car from $10 \, m/s$ to $20 \, m/s$ is how many times the energy required to accelerate the car from rest to $10 \, m/s$?

If the line $y=2x+c$ is a tangent to the circle $x^2+y^2=5$,then a value of $c$ is

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo