Explain the reaction quotient and how it is used to predict the direction of a reaction.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) The equilibrium constants $K_{c}$ and $K_{p}$ help in predicting the direction in which a given reaction will proceed at any stage.
For this,we calculate the reaction quotient $Q$ ($Q_{c}$ for molar concentrations and $Q_{p}$ for partial pressures).
It is defined in the same way as $K_{c}$,except that the concentrations in $Q_{c}$ are not necessarily equilibrium values.
For a general reaction: $aA + bB \rightleftharpoons cC + dD$
$Q_{c} = \frac{[C]^{c}[D]^{d}}{[A]^{a}[B]^{b}}$
$(i)$ If $Q_{c} < K_{c}$,the reaction will proceed in the forward direction (towards products).
$(ii)$ If $Q_{c} > K_{c}$,the reaction will proceed in the reverse direction (towards reactants).
$(iii)$ If $Q_{c} = K_{c}$,the reaction mixture is at equilibrium.
Example: Consider the gaseous reaction $H_{2(g)} + I_{2(g)} \rightleftharpoons 2HI_{(g)}$,where $K_{c} = 57.0$ at $700 \ K$. If the concentrations at an arbitrary time $t$ are $[H_{2}]_{t} = 0.1 \ M$,$[I_{2}]_{t} = 0.2 \ M$,and $[HI]_{t} = 0.40 \ M$,then:
$Q_{c} = \frac{[HI]^{2}}{[H_{2}][I_{2}]} = \frac{(0.40)^{2}}{(0.1)(0.2)} = \frac{0.16}{0.02} = 8.0$
Since $Q_{c} < K_{c}$,the reaction will proceed in the forward direction to form more $HI$ until $Q_{c} = K_{c}$.

Explore More

Similar Questions

Explain why pure liquids and solids can be ignored while writing the equilibrium constant expression?

The equilibrium constant of the following reaction is $0.5$. $CO_{(g)} + 2H_{2(g)} \rightleftharpoons CH_3OH_{(g)}$. At equilibrium,$[CO] = 0.18 \ mol \ L^{-1}$ and $[H_2] = 0.22 \ mol \ L^{-1}$. Calculate the concentration of $CH_3OH$.

For the reaction $A + 2B \rightleftharpoons C$,the expression for equilibrium constant is

An equilibrium mixture of the reaction $2H_2S_{(g)} \rightleftharpoons 2H_{2(g)} + S_{2(g)}$ had $0.5 mol$ $H_2S$,$0.10 mol$ $H_2$,and $0.4 mol$ $S_2$ in a $1 L$ vessel. The value of the equilibrium constant $(K_c)$ in $mol L^{-1}$ is:

For the reaction,$N_{2(g)} + O_{2(g)} \rightleftharpoons 2NO_{(g)}$,the equilibrium constant is $K_1$. The equilibrium constant is $K_2$ for the reaction,$2NO_{(g)} + O_{2(g)} \rightleftharpoons 2NO_{2(g)}$. What is $K$ for the reaction,$NO_{2(g)} \rightleftharpoons \frac{1}{2} N_{2(g)} + O_{2(g)}$?

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo