Draw an energy profile diagram for a three-step reaction in which the first step is the slowest and the last step is the fastest. (Assume that the reaction is exothermic)

  • A
    Option A
  • B
    Option B
  • C
    Option C
  • D
    None of these

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In the reaction of decomposition of reactant $A$ into product,the rate constant is $4.5 \times 10^{-3} \ s^{-1}$ at $283 \ K$ temperature and energy of activation is $60 \ kJ \ mol^{-1}$. At which temperature will the value of rate constant $K$ be $3 \times 10^{10} \ s^{-1}$ (in $K$)?

For a first-order reaction,the time taken to complete $10\%$ at $298\, K$ is equal to the time taken to complete $25\%$ at $308\, K$. The activation energy of the reaction is ................ $kJ/mol$.

The first order rate constant for the decomposition of $CaCO_3$ at $700 \ K$ is $6.36 \times 10^{-3} \ s^{-1}$ and activation energy is $209 \ kJ \ mol^{-1}$. Its rate constant (in $s^{-1}$) at $500 \ K$ is $x \times 10^{-6}$. The value of $x$ is ..... (Nearest integer)
Given $R=8.31 \ J \ K^{-1} \ mol^{-1} ; \log(6.36 \times 10^{-3})=-2.19 ; [10^{-4.79}=1.62 \times 10^{-5}]$

Consider the following statements related to the temperature dependence of rate constants. Identify the correct statements:
$A.$ The Arrhenius equation holds true only for an elementary homogeneous reaction.
$B.$ The unit of $A$ is the same as that of $k$ in the Arrhenius equation.
$C.$ At a given temperature,a low activation energy means a fast reaction.
$D.$ $A$ and $E_a$ as used in the Arrhenius equation depend on temperature.
$E.$ When $E_a > RT$,$A$ and $E_a$ become interdependent.
Choose the correct answer from the options given below:

$A$ sample of milk splits after $60 \; min.$ at $300 \; K$ and after $40 \; min.$ at $400 \; K$ when the population of $Lactobacillus \; acidophilus$ in it doubles. The activation energy (in $kJ / mol$) for this process is closest to ............. $kJ / mol$.
(Given: $R = 8.3 \; J \; mol^{-1} \; K^{-1}$,$\ln(1.5) = 0.405$)

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