Discuss the various reactions that occur in the Solvay process.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
The Solvay process is used for the industrial preparation of sodium carbonate $(Na_2CO_3)$.
Step $1$: Brine solution ($NaCl$ solution) is saturated with ammonia $(NH_3)$.
$2NH_3 + H_2O + CO_2 \longrightarrow (NH_4)_2CO_3$
Step $2$: Carbon dioxide is passed through the ammoniated brine to form insoluble sodium hydrogen carbonate $(NaHCO_3)$.
$NH_3 + H_2O + CO_2 \longrightarrow NH_4HCO_3$
$NaCl + NH_4HCO_3 \longrightarrow NaHCO_3 \downarrow + NH_4Cl$
Step $3$: The $NaHCO_3$ crystals are separated by filtration.
Step $4$: $NaHCO_3$ is heated strongly to obtain sodium carbonate $(Na_2CO_3)$.
$2NaHCO_3 \longrightarrow Na_2CO_3 + CO_2 + H_2O$
Step $5$: Ammonia is recovered by treating the filtrate (containing $NH_4Cl$) with calcium hydroxide $(Ca(OH)_2)$.
$Ca(OH)_2 + 2NH_4Cl \longrightarrow 2NH_3 + 2H_2O + CaCl_2$
The overall reaction is:
$2NaCl + CaCO_3 \longrightarrow Na_2CO_3 + CaCl_2$

Explore More

Similar Questions

Magnesium liberates $H_2$ gas on reaction with

The electronic configuration of a metal is $1s^2 2s^2 2p^6 3s^1$. The formula of its oxide is:

Which of the following orders is correct with respect to the magnitude of enthalpies of formation for alkali metal halides?

Difficult
View Solution

Starting with sodium chloride,how would you proceed to prepare:
$(i)$ sodium metal
$(ii)$ sodium hydroxide
$(iii)$ sodium peroxide
$(iv)$ sodium carbonate?

Difficult
View Solution

Which of the following statements is not true for most of the alkali metals?

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo