Derive the equation for the ionization constant $K_a$ of a weak acid $HX$.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) weak acid $HX$ is partially ionized in an aqueous solution. The equilibrium is expressed as:
$HX_{(aq)} + H_2O_{(l)} \rightleftharpoons H_3O_{(aq)}^{+} + X_{(aq)}^{-}$
Initial Concentration $(M)$: $C, 0, 0$
Change in concentration: $-C\alpha, +C\alpha, +C\alpha$
Concentration at equilibrium: $C(1-\alpha), C\alpha, C\alpha$
where $\alpha$ is the degree of ionization.
The equilibrium constant expression is:
$K = \frac{[H_3O^{+}][X^{-}]}{[HX][H_2O]}$
Since $[H_2O]$ is constant in dilute solutions,we define the acid dissociation constant $K_a$ as:
$K_a = K[H_2O] = \frac{[H_3O^{+}][X^{-}]}{[HX]}$
Substituting the equilibrium concentrations:
$K_a = \frac{(C\alpha)(C\alpha)}{C(1-\alpha)}$
$K_a = \frac{C^2\alpha^2}{C(1-\alpha)} = \frac{C\alpha^2}{1-\alpha}$
This is the expression for the ionization constant of a weak acid.

Explore More

Similar Questions

The $pH$ of a $0.1 \ M$ solution of the acid $HQ$ is $3$. The value of the ionization constant,$K_a$ of the acid is:

The $pH$ of a $0.01 \ M$ weak acid $HX$ $(K_{a}=4 \times 10^{-10})$ is found to be $5$. Now the acid solution is diluted with excess of water so that the $pH$ of the solution changes to $6$. The new concentration of the diluted weak acid is given as $x \times 10^{-4} \ M$. The value of $x$ is $...........$ (nearest integer)

$A$ weak base is $1.42 \%$ dissociated in its $0.05 \ M$ solution. Calculate its dissociation constant.

Calculate the ionisation constant of $0.08 \ mol \ dm^{-3}$ of a monobasic acid having $pH = 2$.

The hydrogen ion concentration in a weak acid of dissociation constant $K_a$ and concentration $c$ is nearly equal to:

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo