Consider the following reversible reaction,
$A_{(g)} + B_{(g)} \rightleftharpoons AB_{(g)}.$
The activation energy of the backward reaction exceeds that of the forward reaction by $2RT$ (in $J \ mol^{-1}$). If the pre-exponential factor of the forward reaction is $4$ times that of the reverse reaction,the absolute value of $\Delta G^{\ominus}$ (in $J \ mol^{-1}$) for the reaction at $300 \ K$ is. . . . . (Given; $\ln(2)=0.7, RT=2500 \ J \ mol^{-1}$ at $300 \ K$ and $G$ is the Gibbs energy)
$A_{(g)} + B_{(g)} \rightleftharpoons AB_{(g)}.$
The activation energy of the backward reaction exceeds that of the forward reaction by $2RT$ (in $J \ mol^{-1}$). If the pre-exponential factor of the forward reaction is $4$ times that of the reverse reaction,the absolute value of $\Delta G^{\ominus}$ (in $J \ mol^{-1}$) for the reaction at $300 \ K$ is. . . . . (Given; $\ln(2)=0.7, RT=2500 \ J \ mol^{-1}$ at $300 \ K$ and $G$ is the Gibbs energy)
- A$8500$
- B$8800$
- C$900$
- D$1000$
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Medium
View Solution$A \rightarrow B$. The molecule $A$ changes into its isomeric form $B$ following first-order kinetics at a temperature of $1000 \ K$. If the energy barrier with respect to reactant energy for such isomeric transformation is $191.48 \ kJ \ mol^{-1}$ and the frequency factor is $10^{20} \ s^{-1}$,the time required for $50 \%$ of molecules of $A$ to become $B$ is $..............$ picoseconds (nearest integer). $[R = 8.314 \ J \ K^{-1} \ mol^{-1}]$
DifficultJEE MAIN 2025
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