Consider the following gaseous equilibrium reactions $(I)$,$(II)$ and $(III)$ with equilibrium constants $K_1$,$K_2$ and $K_3$ respectively:
$I$) $\frac{1}{2} N_2 + \frac{3}{2} H_2 \rightleftharpoons NH_3$
$II$) $2 NO \rightleftharpoons N_2 + O_2$
$III$) $H_2 + \frac{1}{2} O_2 \rightleftharpoons H_2 O$
The correct expression for the equilibrium constant for the gaseous equilibrium reaction $2 NH_3 + \frac{5}{2} O_2 \rightleftharpoons 2 NO + 3 H_2 O$ is

  • A
    $\frac{K_3^3}{K_1^2 \times K_2}$
  • B
    $\frac{K_3^2}{K_1^2 \times K_2}$
  • C
    $\frac{K_3^3}{K_1 \times K_2}$
  • D
    $\frac{K_3^2}{K_1 \times K_2}$

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$A$ sample of pure $PCl_{5}$ was introduced into an evacuated vessel at $473 \, K$. After equilibrium was attained,the concentration of $PCl_{5}$ was found to be $0.5 \times 10^{-1} \, mol \, L^{-1}$. If the value of $K_{c}$ is $8.3 \times 10^{-3}$,what are the concentrations of $PCl_{3}$ and $Cl_{2}$ at equilibrium?
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