Consider a reversible reaction $2A + B \rightleftharpoons 2C$ having equilibrium constant $K_c = 25$. If a reaction vessel contains $2 \ mol$ of $A$,$0.25 \ mol$ of $B$,and $0.5 \ mol$ of $C$ in a $100 \ L$ vessel,what will be the direction of the reaction?

  • A
    Forward
  • B
    Backward
  • C
    Exist in equilibrium
  • D
    Can't predict

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One mole of $N_2O_4(g)$ is taken in a closed container at $1 \ atm$ and $300 \ K$. When it is heated to $600 \ K$,$20 \%$ of $N_2O_4(g)$ dissociates into $NO_2(g)$. The resulting pressure is .......... $atm$.

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The equilibrium constant for the following reaction is $1.6 \times 10^{5}$ at $1024 \, K$:
$H_{2(g)} + Br_{2(g)} \longleftrightarrow 2HBr_{(g)}$
Find the equilibrium pressure of all gases if $10.0 \, bar$ of $HBr$ is introduced into a sealed container at $1024 \, K$.

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The reaction $2H_2S_{(g)} \rightleftharpoons 2H_{2_{(g)}} + S_{2_{(g)}}$ is in equilibrium. If $0.5 \ mol$ of $H_2S$,$0.10 \ mol$ of $H_2$,and $0.4 \ mol$ of $S_2$ are taken in a $1 \ L$ vessel,the value of the equilibrium constant $(K)$ is .... $mol \ L^{-1}$.

The amount of $PCl_5$ (in moles) that needs to be added to a $1\,L$ vessel at $250\,^oC$ in order to obtain $0.1\,mol$ of $Cl_2$ for the given reaction is:
$PCl_5(g) \rightleftharpoons PCl_3(g) + Cl_2(g)$; $K_C = 0.0414\,mol\,L^{-1}$

Calculate:
$(a)$ $\Delta G^{\circ}$ and
$(b)$ the equilibrium constant for the formation of $NO_2$ from $NO$ and $O_2$ at $298 \, K$
$NO_{(g)} + 1/2 O_{2(g)} \longleftrightarrow NO_{2(g)}$
Given:
$\Delta G^{\circ}_f(NO_2) = 52.0 \, kJ/mol$
$\Delta G^{\circ}_f(NO) = 87.0 \, kJ/mol$
$\Delta G^{\circ}_f(O_2) = 0 \, kJ/mol$

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