Identify the complex compound$(s)$ which is/are optically active and whose optical activity does not depend upon the orientation of the ligands around the metal cation:
$(i). [CoCl_3(NH_3)_3]$
$(ii). [Co(en)_3]Cl_3$
$(iii). [Co(C_2O_4)_2(NH_3)_2]^-$
$(iv). [CrCl_2(NH_3)_2(en)]^+$

  • A
    only $(ii)$
  • B
    $(i), (ii)$ and $(iv)$
  • C
    $(ii)$ and $(iv)$
  • D
    $(ii), (iii)$ and $(iv)$

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Similar Questions

Calculate the magnetic moment of the $Fe^{3+}$ ion in the $[Fe(CN)_6]^{3-}$ complex.

Select the correct code of $TRUE$ and $FALSE$ for the given statements:
$(a)$ Peroxide ion as well as dioxygen molecule both are paramagnetic species.
$(b)$ In the set of isomers,$[Cr(H_2O)_6]Cl_3$ and $[CrCl(H_2O)_5]Cl_2 \cdot H_2O$,both compounds can easily lose water molecules on treatment with conc. $H_2SO_4$.
$(c)$ During the transformation $NO \to NO^+$,bond length decreases and magnetic behavior changes from paramagnetic to diamagnetic.
$(d)$ An ether is more volatile than an alcohol,both having the same molecular formula.

Difficult
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The magnetic moment of $[NiCl_4]^{2-}$ is .... $B.M.$ (spin-only).

Match List-$I$ with List-$II$ :-
List-$I$ (Coordination compounds) List-$II$ (Number of unpaired electrons)
$A$. $[Cr(CN)_6]^{3-}$ $I$. $0$
$B$. $[Fe(H_2O)_6]^{2+}$ $II$. $3$
$C$. $[Co(NH_3)_6]^{3+}$ $III$. $2$
$D$. $[Ni(NH_3)_6]^{2+}$ $IV$. $4$

Choose the correct answer from the options given below :-

Which of the following complex ions exhibits geometrical isomerism?

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