Carbon donor ligands are strong ligands and usually form low spin complexes. Among the complexes given below,select the high spin complex.

  • A
    $[Fe(CN)_6]^{3-}$
  • B
    $[Fe(CN)_6]^{4-}$
  • C
    $[Fe(C_2O_4)_3]^{3-}$
  • D
    none of these

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The correct increasing order for the wavelengths of absorption in the visible region for the complexes of $Co^{3+}$ is:

Arrange the following ligands in the order of increasing field strength:
$H_2O$ $(I)$,$CO$ $(II)$,$NH_3$ $(III)$,$I^{-}$ $(IV)$,$F^{-}$ $(V)$

Using crystal field theory,draw energy level diagrams,write the electronic configuration of the central metal atom/ion,and determine the magnetic moment value for the following:
$(i)$ $[CoF_{6}]^{3-}, [Co(H_{2}O)_{6}]^{2+}, [Co(CN)_{6}]^{3-}$
$(ii)$ $[FeF_{6}]^{3-}, [Fe(H_{2}O)_{6}]^{2+}, [Fe(CN)_{6}]^{4-}$

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Crystal field stabilization energy for complex $[Co(CN)_6]^{3-}$ will be

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