Calculate the heat of formation of $PCl_{5(s)}$ from the following data:
$2P_{(s)} + 3Cl_{2(g)} \to 2PCl_{3(l)}; \Delta H_1 = -151.8 \ kcal$
$PCl_{3(l)} + Cl_{2(g)} \to PCl_{5(s)}; \Delta H_2 = -32.8 \ kcal$
Determine the enthalpy of formation for $PCl_{5(s)}$ in $kcal$.

The bond dissociation enthalpy of $X_2$,$\Delta H_{\text{bond}}^{\circ}$,calculated from the given data is $...$ $kJ \ mol^{-1}$. (Nearest integer)
$M^{+}X^{-}_{(s)} \rightarrow M^{+}_{(g)} + X^{-}_{(g)} \quad \Delta H_{\text{lattice}}^{\circ} = 800 \ kJ \ mol^{-1}$
$M_{(s)} \rightarrow M_{(g)} \quad \Delta H_{\text{sub}}^{\circ} = 100 \ kJ \ mol^{-1}$
$M_{(g)} \rightarrow M^{+}_{(g)} + e^{-}_{(g)} \quad \Delta H_{i}^{\circ} = 500 \ kJ \ mol^{-1}$
$X_{(g)} + e^{-}_{(g)} \rightarrow X^{-}_{(g)} \quad \Delta H_{\text{eg}}^{\circ} = -300 \ kJ \ mol^{-1}$
$M_{(s)} + \frac{1}{2}X_{2(g)} \rightarrow M^{+}X^{-}_{(s)} \quad \Delta H_{f}^{\circ} = -400 \ kJ \ mol^{-1}$
[Given : $M^{+}X^{-}$ is a pure ionic compound and $X$ forms a diatomic molecule $X_2$ in gaseous state]

Which of the following reactions is exothermic?

The heat of neutralisation of one equivalent of an acid by one equivalent of a base is minimum when:

The following thermochemical reactions are given:
$M + \frac{1}{2} O_2 \to MO + 351.4 \ kJ$ $(i)$
$X + \frac{1}{2} O_2 \to XO + 90.8 \ kJ$ $(ii)$
It follows that the heat of reaction for the following process $M + XO \rightleftharpoons MO + X$ is given by $... \ kJ$.

The heats of solution of anhydrous $CuSO_4$ and $CuSO_4 \cdot 5H_2O$ are $-15.89 \, kcal \, mol^{-1}$ and $2.80 \, kcal \, mol^{-1}$ respectively. What is the heat of hydration of anhydrous $CuSO_4$ in $kcal \, mol^{-1}$?