Boron can be obtained by various methods but not by

  • A
    thermal decomposition of $B_2H_6$
  • B
    pyrolysis of $BI_3$ (van Arkel)
  • C
    reducing $BCl_3$ with $H_2$
  • D
    electrolysis of fused $BCl_3$

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$BCl_3$ exists as a monomer,whereas $AlCl_3$ is dimerized through halogen bridging. Give reason. Explain the structure of the dimer of $AlCl_3$ also.

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In the following reaction,assign the correct category for the underlined atom in the product of complete hydrolysis at $R.T.$:
$\underline{I}Cl_3 + H_2O \longrightarrow HIO_2 + HCl$

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The tendency of $BF_3$,$BCl_3$ and $BBr_3$ to behave as Lewis acid decreases in the sequence

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